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Vodka

Title text: Or whatever's handy! I'm pretty much pure alcohol and water, so it doesn't really matter!

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Explanation

When most people say "it's the vodka talking" (or similar phrases), they mean that they are speaking under the influence of alcohol.

However, in this comic, it is as if the substance of vodka itself is taking, and discussing its origin (potatoes).

Ponytail: Maybe this is the vodka talking, but:

Ponytail: Hi! I'm made from potatoes!